Advanced Ceramics Progress

Advanced Ceramics Progress

Exploring the Potential of ZnS/CdS Dual Nanocomposites in Photocatalytic Degradation for Water Cleanup

Document Type : Original Research Article

Authors
1 BSc Student, Faculty of Materials and Metallurgical Engineering, University of Semnan, Iran.
2 Research Assistant, Faculty of Materials and Metallurgical Engineering, University of Semnan, Iran.
3 Assistant Professor, Department of Nanotechnology, Faculty of New Sciences and Technologies, University of Semnan, Iran.
4 Professor, Faculty of Materials & Metallurgical Engineering, University of Semnan, Iran.
Abstract
The use of photocatalytic degradation to address environmental cleanup issues is gaining popularity. In this work, pure ZnS, CdS, and ZnS/CdS heterostructure nanocomposites with superior photocatalyst efficiency were synthesized using a straightforward coprecipitation technique and a solvothermal process. The structural, morphological, and optical characteristics were analyzed using XRD, EDX, FTIR, FESEM, and UV-Vis absorbance measurement techniques. The XRD data indicated that ZnS/CdS nanocomposites were produced with an average crystallite size of 15–20 nm. The UV-Vis measurements revealed an optical band gap ranging from 4.4 eV to 5.3 eV. The photocatalytic efficacy of the ZnS/CdS heterostructure nanocomposites in degrading methylene blue (MB) dye was evaluated under UVA light. The synthesized ZnS/CdS nanocomposite exhibited remarkable decolorization efficiency (99%) within just 5 minutes of UVA light exposure. This straightforward method has the potential to be scaled up for industrial applications.
Keywords

Subjects


  1. Afzali, A. H., Seddiqi, A., Akbari, Z., Hajiebrahimi, M., Alamdari, S., & Mirzaee, O. (2024). Synthesis and characterization of ZnS and Ag-ZnS nanoparticles for photocatalytic degradation of aqueous pollutants. Synthesis and Sintering, 4(4), 248-255. https://doi.org/10.53063/synsint.2024.44258
  2. Alamdari, S., Haji Ebrahimi, M., Mirzaee, O., Jafar Tafreshi, M., Majlesara, M. H., Tajally, M., ... & Mohammadi, A. (2022). Cerium doped tungsten-based compounds for thermoluminescence application. Progress in Physics of Applied Materials, 2(1), 35-40. https://doi.org/10.22075/ppam.2022.27086.1028.
  3. Amma, B. S., Manzoor, K., Ramakrishna, K., & Pattabi, M. (2008). Synthesis and optical properties of CdS/ZnS coreshell nanoparticles. Materials Chemistry and Physics, 112(3), 789-792. https://doi.org/10.1016/j.matchemphys.2008.06.043
  4. Chen, X., Lin, P., Yan, X., Bai, Z., Yuan, H., Shen, Y., ... & Zhang, Y. (2015). Three-dimensional ordered ZnO/Cu2O nanoheterojunctions for efficient metal–oxide solar cells. ACS applied materials & interfaces, 7(5), 3216-3223. https://doi.org/10.1021/am507836v
  5. El-Bially, A. B., Seoudi, R., Eisa, W., Shabaka, A. A., Abd El-Hamid, R. K., & Ramadan, R. A. (2012). Preparation, characterization and physical properties of CdS nanoparticles with different sizes. Journal of Applied Sciences Research, 8(2), 676-685. https://www.researchgate.net/publication/259327880
  6. Esparza, D., Lopez-Luke, T., Oliva, J., Cerdán-Pasarán, A., Martínez-Benítez, A., Mora-Seró, I., & De la Rosa, E. (2017). Enhancement of efficiency in quantum dot sensitized solar cells based on CdS/CdSe/CdSeTe heterostructure by improving the light absorption in the VIS-NIR region. Electrochimica Acta, 247, 899-909. https://doi.org/10.1016/j.electacta.2017.07.060
  7. Estévez-Hernández, O., González, J., Guzmán, J., Santiago-Jacinto, P., Rendón, L., Montes, E., & Reguera, E. (2012). Mercaptopropionic Acid Capped CdS@ ZnS Nanocomposites: Interface Structure and Related Optical Properties. Science of Advanced Materials, 4(7), 771-779. https://doi.org/10.1166/sam.2012.1372
  8. Farahani, M. M. H., Hajiebrahimi, M., Alamdari, S., Najafzadehkhoee, A., Khounsaraki, G. M., Agheb, M., ... & Mirzaee, O. (2024). Synthesis and antibacterial activity of silver doped zinc sulfide/chitosan bionanocomposites: A new frontier in biomedical applications. International Journal of Biological Macromolecules, 280, 135934. https://doi.org/10.1016/j.ijbiomac.2024.135934
  9. Hajiebrahimi, M., Alamdari, S., & Mirzaee, O. (2024). The Potential of Silver-Doped Zinc Sulfide/Cadmium Sulfide Nanocomposites in Optoelectronic Applications. Iranian Journal of Materials Science and Engineering21(4). http://ijmse.iust.ac.ir/article-1-3784-en.html
  10. Hajiebrahimi, M., Alamdari, S., Mirzaee, O., & Tajally, M. (2022). Luminescence investigation of Ce doped ZnO/CdWO4 Advanced Ceramics Progress, 8(3), 8-12. https://doi.org/10.30501/acp.2022.363264.1102.
  11. Hajiebrahimi, M., Alamdari, S., Mirzaee, O., Albov, D., & Hvizdos, P. (2025). Flexible cerium-doped tungstate oxide/titanium dioxide nanocomposite for high-sensitivity energy conversion in optical applications. Journal of Materials Science: Materials in Electronics36(2), 103. https://doi.org/10.1007/s10854-024-14141-8
  12. Kannan, S., Subiramaniyam, N. P., & Sathishkumar, M. (2020). Effect of annealing temperature and Mn doping on the structural and optical properties of ZnS thin films for enhanced photocatalytic degradation under visible light irradiation. Inorganic Chemistry Communications, 119, 108068. https://doi.org/10.1016/j.inoche.2020.108068
  13. Kim, M. R., Kang, Y. M., & Jang, D. J. (2007). Synthesis and characterization of highly luminescent CdS@ ZnS core− shell nanorods. The Journal of Physical Chemistry C, 111(50), 18507-18511. https://doi.org/10.1021/jp075218n
  14. Li, B., & Wang, Y. (2011). Synthesis, microstructure, and photocatalysis of ZnO/CdS nano-heterostructure. Journal of Physics and Chemistry of Solids, 72(10), 1165-1169. https://doi.org/10.1016/j.jpcs.2011.07.010
  15. Li, F., Jiang, Y., Hu, L., Liu, L., Li, Z., & Huang, X. (2009). Structural and luminescent properties of ZnO nanorods and ZnO/ZnS nanocomposites. Journal of alloys and compounds, 474(1-2), 531-535. https://doi.org/10.1016/j.jallcom.2008.06.149
  16. Li, L., Daou, T. J., Texier, I., Kim Chi, T. T., Liem, N. Q., & Reiss, P. (2009). Highly luminescent CuInS2/ZnS core/shell nanocrystals: cadmium-free quantum dots for in vivo imaging. Chemistry of Materials, 21(12), 2422-2429. https://doi.org/10.1021/cm900103b
  17. Li, Q., Meng, H., Zhou, P., Zheng, Y., Wang, J., Yu, J., & Gong, J. (2013). Zn1–x Cd x S solid solutions with controlled bandgap and enhanced visible-light photocatalytic H2-production activity. Acs Catalysis, 3(5), 882-889. https://doi.org/10.1021/cs4000975
  18. Li, X., Wang, P., Huang, B., Qin, X., Zhang, X., Zhang, Q., ... & Dai, Y. (2017). Precisely locate Pd-Polypyrrole on TiO2 for enhanced hydrogen production. International Journal of Hydrogen Energy, 42(40), 25195-25202. https://doi.org/10.1016/j.ijhydene.2017.08.153
  19. Luo, Z., Zhao, X., Zhang, H., & Jiang, Y. (2019). 3Cd0. 7S nanorods loaded with noble-metal-free Ni3C co-catalyst enhancing photocatalytic hydrogen evolution. Applied Catalysis A: General, 582, 117115. https://doi.org/10.1016/j.apcata.2019.117115
  20. Madhavi, J., Prasad, V., Reddy, K. R., Reddy, C. V., & Raghu, A. V. (2021). Facile synthesis of Ni-doped ZnS-CdS composite and their magnetic and photoluminescence properties. Journal of Environmental Chemical Engineering9(6), 106335. https://doi.org/10.1016/j.jece.2021.106335
  21. Malik, M. A., O'Brien, P., & Revaprasadu, N. (2002). A simple route to the synthesis of core/shell nanoparticles of chalcogenides. Chemistry of Materials, 14(5), 2004-2010. https://doi.org/10.1021/cm011154w
  22. Mangla, D., Abbasi, A., Aggarwal, S., Manzoor, K., Ahmad, S., & Ikram, S. (2019). Effective removal of “non-biodegradable” pollutants from contaminated water. Metal oxide-based photocatalyst for the degradation of organic pollutants in water, 159. https://www.researchgate.net/publication/346426091
  23. Mumin, M. A., Moula, G., & Charpentier, P. A. (2015). Supercritical CO 2 synthesized TiO 2 nanowires covalently linked with core–shell CdS–ZnS quantum dots: enhanced photocatalysis and stability. RSC Advances, 5(83), 67767-67779. https://doi.org/10.1039/C5RA08914J
  24. Nizamoglu, S., Ozel, T., Sari, E., & Demir, H. V. (2007). White light generation using CdSe/ZnS core–shell nanocrystals hybridized with InGaN/GaN light emitting diodes. Nanotechnology, 18(6), 065709. https://doi.org/10.1088/0957-4484/18/6/065709
  25. Pei, L., Liu, J., Xu, Y., Han, Y., Wu, J., Wang, Z., & Zhang, X. (2019). Hierarchical Zn1-xCdxS microclusters with superior visible-light-driven photocatalytic hydrogen generation performance. Journal of Alloys and Compounds, 809, 151869. https://doi.org/10.1016/j.jallcom.2019.151869
  26. Reiss, P., Protiere, M., & Li, L. (2009). Core/shell semiconductor nanocrystals. small, 5(2), 154-168. https://doi.org/10.1002/smll.200800841
  27. Schattka, J. H., Shchukin, D. G., Jia, J., Antonietti, M., & Caruso, R. A. (2002). Photocatalytic activities of porous titania and titania/zirconia structures formed by using a polymer gel templating technique. Chemistry of Materials, 14(12), 5103-5108. https://doi.org/10.1021/cm021238k
  28. Shuai, X. M., & Shen, W. Z. (2011). A facile chemical conversion synthesis of ZnO/ZnS core/shell nanorods and diverse metal sulfide nanotubes. The Journal of Physical Chemistry C, 115(14), 6415-6422. https://doi.org/10.1021/jp2005716
  29. Soltani, N., Saion, E., Hussein, M. Z., Erfani, M., Abedini, A., Bahmanrokh, G., ... & Vaziri, P. (2012). Visible light-induced degradation of methylene blue in the presence of photocatalytic ZnS and CdS nanoparticles. International journal of molecular sciences, 13(10), 12242-12258. https://doi.org/10.3390/ijms131012242
  30. Suárez, P. L., García-Cortés, M., Fernández-Argüelles, M. T., Encinar, J. R., Valledor, M., Ferrero, F. J., ... & Costa-Fernández, J. M. (2019). Functionalized phosphorescent nanoparticles in (bio) chemical sensing and imaging–a review. Analytica chimica acta, 1046, 16-31. https://doi.org/10.1016/j.aca.2018.08.018
  31. Yang, H., Huang, C., Su, X., & Tang, A. (2005). Microwave-assisted synthesis and luminescent properties of pure and doped ZnS nanoparticles. Journal of Alloys and Compounds, 402(1-2), 274-277. https://doi.org/10.1016/j.jallcom.2005.04.150
  32. Yuan, Y. J., Chen, D., Yu, Z. T., & Zou, Z. G. (2018). Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production. Journal of Materials Chemistry A, 6(25), 11606-11630. https://doi.org/10.1039/C8TA00671G
  33. Yuan, Y. J., Li, Z., Wu, S., Chen, D., Yang, L. X., Cao, D., ... & Zou, Z. G. (2018). Role of two-dimensional nanointerfaces in enhancing the photocatalytic performance of 2D-2D MoS2/CdS photocatalysts for H2 production. Chemical Engineering Journal, 350, 335-343. https://doi.org/10.1016/j.cej.2018.05.172
  34. Zhai, X., Zhang, R., Lin, J., Gong, Y., Tian, Y., Yang, W., & Zhang, X. (2015). Shape-controlled CdS/ZnS core/shell heterostructured nanocrystals: synthesis, characterization, and periodic DFT calculations. Crystal Growth & Design, 15(3), 1344-1350. https://doi.org/10.1021/cg501747e
  35. Zhang, J., Xiao, M., Liu, Z., Han, B., Jiang, T., He, J., & Yang, G. (2004). Preparation of ZnS/CdS composite nanoparticles by coprecipitation from reverse micelles using CO2 as antisolvent. Journal of colloid and interface science, 273(1), 160-164. https://doi.org/10.1016/j.jcis.2004.02.032
  36. Zhang, L., Jiang, D., Irfan, R. M., Tang, S., Chen, X., & Du, P. (2019). Highly efficient and selective photocatalytic dehydrogenation of benzyl alcohol for simultaneous hydrogen and benzaldehyde production over Ni-decorated Zn0. 5Cd0. 5S solid solution. Journal of energy chemistry, 30, 71-77. https://doi.org/10.1016/j.jechem.2018.03.014
  37. Zhang, R., Xie, J., Wang, C., Liu, J., Zheng, X., Li, Y., ... & Su, B. L. (2017). Macroporous ZnO/ZnS/CdS composite spheres as efficient and stable photocatalysts for solar-driven hydrogen generation. Journal of Materials Science, 52, 11124-11134. https://doi.org/10.1007/s10853-017-1130-6
  38. Zhou, X., Zhang, N., Yin, L., Zhao, Y., & Zhang, B. (2020). Few-layered WS2 nanosheets onto 1D CdS@ ZnCdS as efficient visible-light photocatalyst for hydrogen evolution. Ceramics International, 46(16), 26100-26108. https://doi.org/10.1016/j.ceramint.2020.07.105

  • Receive Date 04 November 2024
  • Accept Date 21 December 2024