Ultraviolet Detectors Based on Annealed Zinc Oxide Thin Films: Epitaxial Growth and Physical Characterizations

Document Type : Original Research Article

Authors

Department of semiconductors, Materials and Energy Research Center (MERC), Karaj, Iran

Abstract

In this report, ultraviolet (UV) detectors were fabricated based on zinc oxide thin films. The epitaxial growth of zinc oxide thin films was carried out on a bare glass substrate with a preferred orientation to (002) plane of wurtzite structure through radio frequency sputtering technique. The structural properties indicated a dominant peak at 2θ=34.28º, which was matched with JCPDS reference card No. 34-1451 and showed the wurtzite phase of deposited ZnO thin films. This peak showed the preferred orientation with the c-axis perpendicular to the surface. The crystallite size was estimated using the Scherrer equation as much as 44.5nm. The morphology of samples showed that pebble-shaped ZnO particles were covered on the entire substrate homogeneously. The results indicated the excellent optical properties in the visible-infrared region with high absorption in the UV spectrum. The extrapolated cut-off for the transmittance spectrum was at 373nm, which confirmed the calculated optical bandgap of this sample at 3.27eV. The optical properties showed that the deposited samples are suitable substrates for the fabrication of UV detectors. Two back-to-back Schottky contacts of Au were deposited on the ZnO substrate to fabricate UV detectors, and a metal-semiconductor-metal structure was designed. The optoelectrical properties of detectors were carried out using the measurement of current-voltage curves. The results indicated a high photosensitivity of 0.32 corresponding to the high performance of the fabricated device. Moreover, the device showed a short rise time of 0.40s and recovery time of 0.45s indicating the high speed of detection for fabricated UV detectors.

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1. Sang, L., Liao, M. and Sumiya, M., “A comprehensive review of semiconductor ultraviolet photodetectors: from thin film to one-dimensional nanostructures”, Sensors, Vol. 13, No. 8, (2013), 10482-10518.
2. Daniel, G.P., Justinvictor, V.B., Nair, P.B., Joy, K., Koshy, P. and Thomas, P.V., “Effect of annealing temperature on the structural and optical properties of ZnO thin films prepared by RF magnetron sputtering”, Physica B: Condens Matter, Vol. 405, No. 7, (2010), 1782-1786.
3. Purohit, A., Chander, S., Sharma, A., Nehra, S.P. and Dhaka, M.S., “Impact of low temperature annealing on structural, optical, electrical and morphological properties of ZnO thin films grown by RF sputtering for photovoltaic applications”, Optical Materials, Vol. 49, No. 8, (2015), 51-58.
4. Ondo-Ndong, R., Pascal-Delannoy, F., Boyer, A., Giani, A. and Foucaran, A., “Structural properties of zinc oxide thin films prepared by r.f. magnetron sputtering”, Materials Science and Engineering: B, Vol. 97, No. 1, (2003), 68-73.
5. Liu, K., Sakurai, M. and Aono, M., “ZnO-based ultraviolet photodetectors”, Sensors, Vol. 10, No. 9, (2010), 8604-8634.
6. Kim, K.S., Kim, H.W. and Kim, N.H., “Structural characterization of ZnO films grown on SiO2 by the RF magnetron sputtering”, Physica B: Condensed Matter, Vol. 334, No. 3-4, (2003), 343-346.
7. Besleaga, C., Stan, G.E., Galca, A.C., Ion, L. and Antohe, S., “Double layer structure of ZnO thin films deposited by RF-magnetron sputtering on glass substrate”, Applied surface science, Vol. 258, No. 22, (2012), 8819-8824.
8. Zhang, D.H., Xue, Z.Y. and Wang, Q.P., “The mechanisms of blue emission from ZnO films deposited on glass substrate by r.f. magnetron sputtering”, Journal of Physics D: Applied Physics, Vol. 35, No. 21, (2002), 2837–2840.
9. Kumar, S., Sharma, P. and Sharma., “Structural transition in II-VI nanofilms: Effect of molar ratio on structural, morphological, and optical properties”,Journal of Applied Physics, Vol. 111, No. 11, (2012), 113510.
10. Naderi, N. and Hashim, M.R., “Nanocrystalline SiC sputtered on porous silicon substrate after annealing”, Materials Letters, Vol. 97, (2013), 90–92.
11. Kumar, V., Som, S., Yousif, A., Singh, N., Ntwaeaborwa, O.M., Kapoor, A. and Swart, H.C., “Effect of annealing on the structural, morphological and photoluminescence properties of ZnO thin films prepared by spin coating”, Journal of colloid and interface science, Vol. 428, (2014), 8–15.
12. Barote, M.A., Yadav, A.A. and Masumdar, E.U., “Synthesis, characterization and photoelectrochemical properties of n-CdS thin films”, Physica B: Condensed Matter, Vol. 406, No. 10, (2011), 1865–1871.
13. Moghaddam, M., Naderi, N., Hosseinifard, M., Kazemzadeh, A., “Improved optical and structural properties of cadmium sulfide nanostructures for optoelectronic applications”, Ceramics International, doi: 10.1016/j.ceramint.2019.11.23.