Electrochemical Characterization of Low-Cost Lithium-Iron Orthosilicate Samples as Cathode Materials of Lithium-Ion Battery

Authors

1 Ceramic, Material and Energy Research Center

2 Materials Science and Engineering, Sharif University of Technology

3 Materials Engineering, Sharif University of Technology

4 Public Science, K. N. Toosi University of Technology

5 Chemistry, University of Pavia

Abstract

Lithium-iron-orthosilicate is one of the most promising cathode materials for Li-ion batteries due to its safety, environmental brightness and potentially low cost. In order to produce a low cost cathode material, Li2FeSiO4/C samples are synthesized via sol-gel (SG; one sample) and solid state (SS; two samples with different carbon content), starting from Fe (III) in the raw materials (low pristine materials). The three samples are characterized for purity, structure, and morphology. The electrochemical tests showed the different charge-discharge behaviours of the SS and SG samples. Electrochemical behaviours were investigated in terms of voltage vs. square root of capacity diagrams and their slopes. The best results are obtained with the SS sample containing the larger amount of carbon.

Keywords

Main Subjects


1          Tarascon, J.-M. and Armand, M., "Issues and challenges facing rechargeable lithium batteries". Nature,Vol. 414, 6861, (2001), 359-367.

2          Fisher, C. A., Kuganathan, N. and Islam, M. S., "Defect chemistry and lithium-ion migration in polymorphs of the cathode material Li2MnSiO4". J. Mater. Chem. A,Vol. 1, 13, (2013), 4207-4214.

3          Sun, Y.-K., Myung, S.-T., Park, B.-C., Prakash, J., Belharouak, I. and Amine, K., "High-energy cathode material for long-life and safe lithium batteries". Nature materials,Vol. 8, 4, (2009), 320-324.

4          Nishimura, S.-i., Kobayashi, G., Ohoyama, K., Kanno, R., Yashima, M. and Yamada, A., "Experimental visualization of lithium diffusion in LixFePO4". Nature materials,Vol. 7, 9, (2008), 707-711.

5          Kazazi, M., Iilbeigi, M., Fazlali, A. and Mohammadi, A. H., "Preparation, characterization and stability of Li-ion conducting Li1.5Al0.5Ge1.5(PO4)3 glass-ceramic with NASICON-type structure". Journal of Advanced Ceramics Progress,Vol. 2, 1, (2016), 38-43.

6          Gong, Z. and Yang, Y., "Recent advances in the research of polyanion-type cathode materials for Li-ion batteries". Energy & Environmental Science,Vol. 4, 9, (2011), 3223-3242.

7          Xu, B., Qian, D., Wang, Z. and Meng, Y. S., "Recent progress in cathode materials research for advanced lithium ion batteries". Materials Science and Engineering: R: Reports,Vol. 73, 5, (2012), 51-65.

8          Kalantarian, M. M., Asgari, S., Capsoni, D. and Mustarelli, P., "An ab initio investigation of Li 2 M 0.5 N 0.5 SiO 4 (M, N= Mn, Fe, Co Ni) as Li-ion battery cathode materials". Physical Chemistry Chemical Physics,Vol. 15, (2013), 8035-8041.

9          Nytén, A., Abouimrane, A., Armand, M., Gustafsson, T. and Thomas, J. O., "Electrochemical performance of Li< sub> 2 FeSiO< sub> 4 as a new Li-battery cathode material". Electrochemistry communications,Vol. 7, 2, (2005), 156-160.

10        Nytén, A., Kamali, S., Häggström, L., Gustafsson, T. and Thomas, J. O., "The lithium extraction/insertion mechanism in Li2FeSiO4". Journal of Materials Chemistry,Vol. 16, 23, (2006), 2266-2272.

11        Armstrong, A. R., Kuganathan, N., Islam, M. S. and Bruce, P. G., "Structure and lithium transport pathways in Li2FeSiO4 cathodes for lithium batteries". Journal of the American Chemical Society,Vol. 133, 33, (2011), 13031-13035.

12        Sirisopanaporn, C., Masquelier, C., Bruce, P. G., Armstrong, A. R. and Dominko, R., "Dependence of Li2FeSiO4 Electrochemistry on Structure". Journal of the American Chemical Society,Vol. 133, 5, (2010), 1263-1265.

13        Dominko, R., Arčon, I., Kodre, A., Hanžel, D. and Gaberšček, M., "In-situ XAS study on Li< sub> 2 MnSiO< sub> 4 and Li< sub> 2 FeSiO< sub> 4 cathode materials". Journal of Power Sources,Vol. 189, 1, (2009), 51-58.

14        Zaghib, K., Ait Salah, A., Ravet, N., Mauger, A., Gendron, F. and Julien, C., "Structural, magnetic and electrochemical properties of lithium iron orthosilicate". Journal of Power Sources,Vol. 160, 2, (2006), 1381-1386.

15        Sirisopanaporn, C., Boulineau, A., Hanzel, D., Dominko, R., Budic, B., Armstrong, A. R., Bruce, P. G. and Masquelier, C., "Crystal structure of a new polymorph of Li2FeSiO4". Inorganic chemistry,Vol. 49, 16, (2010), 7446-7451.

16        Gao, K., Zhang, J. and Li, S.-D., "Morphology and electrical properties of Li< sub> 2 FeSiO< sub> 4/C prepared by a vacuum solid-state reaction". Materials Chemistry and Physics, (2013).

17        Huang, X., Li, X., Wang, H., Pan, Z., Qu, M. and Yu, Z., "Synthesis and electrochemical performance of Li< sub> 2 FeSiO< sub> 4/carbon/carbon nano-tubes for lithium ion battery". Electrochimica Acta,Vol. 55, 24, (2010), 7362-7366.

18        Boulineau, A., Sirisopanaporn, C., Dominko, R., Armstrong, A. R., Bruce, P. G. and Masquelier, C., "Polymorphism and structural defects in Li2FeSiO4". Dalton Transactions,Vol. 39, 27, (2010), 6310-6316.

19        Bini, M., Ferrari, S., Ferrara, C., Mozzati, M. C., Capsoni, D., Pell, A. J., Pintacuda, G., Canton, P. and Mustarelli, P., "Polymorphism and magnetic properties of Li2MSiO4 (M= Fe, Mn) cathode materials". Scientific Reports,Vol. 3, (2013).

20        Asadi Tabrizi, R., Hesaraki, S. and Zamanian, A., " Effects of time, temperature and precursor on solid state synthesis of α-TCP". Journal of Advanced Ceramics Progress,Vol. 1, 1, (2015), 36-39.

21        Esfandiari, S., Honarvar Nazari, H., Nemati, A., Kargar Razi, M. and Baghshahi, S., "Characterization of Structural, Optical and Hydrophilicity properties of TiO2 Nano-Powder Synthesized by Sol-Gel Method". Journal of Advanced Ceramics Progress,Vol. 2, 2, (2016), 1-6

22        Zhang, L.-L., Duan, S., Yang, X.-L., Peng, G., Liang, G., Huang, Y.-H., Jiang, Y., Ni, S.-B. and Li, M., "Reduced graphene oxide modified Li2FeSiO4/C composite with enhanced electrochemical performance as cathode material for lithium ion batteries". ACS applied materials & interfaces,Vol. 5, 23, (2013), 12304-12309.

23        Zheng, Z., Wang, Y., Zhang, A., Zhang, T., Cheng, F., Tao, Z. and Chen, J., "Porous Li< sub> 2 FeSiO< sub> 4/C nanocomposite as the cathode material of lithium-ion batteries". Journal of Power Sources,Vol. 198, (2012), 229-235.

24        Hao, H., Wang, J., Liu, J., Huang, T. and Yu, A., "Synthesis, characterization and electrochemical performance of Li< sub> 2 FeSiO< sub> 4/C cathode materials doped by vanadium at Fe/Si sites for lithium ion batteries". Journal of Power Sources,Vol. 210, (2012), 397-401.

25        Chen, W., Lan, M., Zhu, D., Ji, C., Feng, X., Yang, C., Zhang, J. and Mi, L., "Synthesis of Li 2 FeSiO 4/C and its excellent performance in aqueous lithium-ion batteries". Journal of Materials Chemistry A,Vol. 1, 36, (2013), 10912-10917.

26        Shao, B., Abe, Y. and Taniguchi, I., "Synthesis and electrochemical characterization of Li 2 Fe x Mn 1− x SiO 4/C (0≦ x≦ 0.8) nanocomposite cathode for lithium-ion batteries". Powder Technology,Vol. 235, (2013), 1-8.

27        Zhang, S., Deng, C. and Yang, S., "Preparation of nano-Li2FeSiO4 as cathode material for lithium-ion batteries". Electrochemical and Solid-State Letters,Vol. 12, 7, (2009), A136-A139.

28        Zhou, H., Einarsrud, M.-A. and Vullum-Bruer, F., "In situ X-ray diffraction and electrochemical impedance spectroscopy of a nanoporous Li2FeSiO4/C cathode during the initial charge/discharge cycle of a Li-ion battery". Journal of power sources,Vol. 238, (2013), 478-484.

29        Zhou, H., Einarsrud, M.-A. and Vullum-Bruer, F., "High capacity nanostructured Li2FexSiO4/C with Fe hyperstoichiometry for Li-ion batteries". Journal of Power Sources, (2013).

30        Peng, G., Zhang, L.-L., Yang, X.-L., Duan, S., Liang, G. and Huang, Y.-H., "Enhanced electrochemical performance of multi-walled carbon nanotubes modified Li< sub> 2 FeSiO< sub> 4/C cathode material for lithium-ion batteries". Journal of Alloys and Compounds, (2013).

31        Kamon-in, O., Klysubun, W., Limphirat, W., Srilomsak, S. and Meethong, N., "An insight into crystal, electronic, and local structures of lithium iron silicate (Li2FeSiO4) materials upon lithium extraction". Physica B,Vol. 416, (2013), 69–75.

32        Qu, L., Fang, S., Zhang, Z., Yang, L. and Hirano, S.-i., "Li 2 FeSiO 4/C with good performance as cathode material for Li-ion battery". Materials Letters,Vol. 108, (2013), 1-4.

33        Qu, L., Fang, S., Yang, L. and Hirano, S.-i., "Li< sub> 2 FeSiO< sub> 4/C cathode material synthesized by template-assisted sol–gel process with Fe< sub> 2 O< sub> 3 microsphere". Journal of Power Sources,Vol. 217, (2012), 243-247.

34        Kalantarian, M., Oghbaei, M., Asgari, S., Ferrari, S., Capsoni, D. and Mustarelli, P., "Understanding non-ideal voltage behaviour of cathodes for lithium-ion batteries". Journal of Materials Chemistry A,Vol. 2, 45, (2014), 19451-19460.

35        ". Bruker AXS (2005). TOPAS V3.0: General profile and structural analysis software for powder diffraction data.

36        Sirisopanaporn, C., Dominko, R., Masquelier, C., Armstrong, A. R., Mali, G. and Bruce, P. G., "Polymorphism in Li2 (Fe, Mn) SiO4: A combined diffraction and NMR study". Journal of Materials Chemistry,Vol. 21, 44, (2011), 17823-17831.

37        Zhou, H., Einarsrud, M.-A. and Vullum-Bruer, F., "PVA-assisted combustion synthesis and characterization of porous nanocomposite Li< sub> 2 FeSiO< sub> 4/C". Solid State Ionics,Vol. 225, (2012), 585-589.

38        Yang, J., Kang, X., Hu, L., Gong, X., He, D., Peng, T. and Mu, S., "Synthesis and Electrochemical Performance of Li< sub> 2 FeSiO< sub> 4/C/Carbon Nanosphere Composite Cathode Materials for Lithium Ion Batteries". Journal of Alloys and Compounds, (2013).

39        Devaraju, M., Tomai, T. and Honma, I., "Supercritical hydrothermal synthesis of rod like Li< sub> 2 FeSiO< sub> 4 particles for cathode application in lithium ion batteries". Electrochimica Acta,Vol. 109, (2013), 75-81.

40        Chung, Y., Yu, S., Song, M. S., Kim, S.-S. and Cho, W. I., "Structural and Electrochemical Properties of Li 2 Mn 0.5 Fe 0.5 SiO 4/C Cathode Nanocomposite". Bull. Korean Chem. Soc,Vol. 32, 12, (2011), 4205.

41        Dominko, R., Conte, D. E., Hanzel, D., Gaberscek, M. and Jamnik, J., "Impact of synthesis conditions on the structure and performance of Li< sub> 2 FeSiO< sub> 4". Journal of Power Sources,Vol. 178, 2, (2008), 842-847.

42        Shao, B. and Taniguchi, I., "Synthesis of Li< sub> 2 FeSiO< sub> 4/C nanocomposite cathodes for lithium batteries by a novel synthesis route and their electrochemical properties". Journal of Power Sources,Vol. 199, (2012), 278-286.

43        Yan, Z., Cai, S., Miao, L., Zhou, X. and Zhao, Y., "Synthesis and characterization of< i> in situ carbon-coated Li< sub> 2 FeSiO< sub> 4 cathode materials for lithium ion battery". Journal of Alloys and Compounds,Vol. 511, 1, (2012), 101-106.

44        Zhu, H., Wu, X., Zan, L. and Zhang, Y., "Superior electrochemical capability of Li 2 FeSiO 4/C/G composite as cathode material for Li-ion batteries". Electrochimica Acta,Vol. 117, (2014), 34-40.

45        Kalantarian, M. M., Asgari, S. and Mustarelli, P., "A theoretical approach to evaluate the rate capability of Li-ion battery cathode materials". Journal of Materials Chemistry A,Vol. 2, 1, (2014), 107-115.

46        Kang, B. and Ceder, G., "Battery materials for ultrafast charging and discharging". Nature,Vol. 458, 7235, (2009), 190-193.

47        Bai, J., Gong, Z., Lv, D., Li, Y., Zou, H. and Yang, Y., "Nanostructured 0.8 Li2FeSiO4/0.4 Li2SiO3/C composite cathode material with enhanced electrochemical performance for lithium-ion batteries". Journal of Materials Chemistry,Vol. 22, 24, (2012), 12128-12132.

48        Song, M.-S., Kim, D.-Y., Kang, Y.-M., Kim, Y.-I., Lee, J.-Y. and Kwon, H.-S., "Amphoteric effects of Fe< sub> 2 P on electrochemical performance of lithium iron phosphate–carbon composite synthesized by ball-milling and microwave heating". Journal of Power Sources,Vol. 180, 1, (2008), 546-552.

49        Kalantarian, M. M., Asgari, S. and Mustarelli, P., "A theoretical approach to evaluate rate capability of Li-ion battery cathode materials". J. Mater. Chem. A, (2013).

50        Dominko, R., Bele, M., Kokalj, A., Gaberscek, M. and Jamnik, J., "Li< sub> 2 MnSiO< sub> 4 as a potential Li-battery cathode material". journal of Power Sources,Vol. 174, 2, (2007), 457-461.